Yang-Yang anomaliya izokhornoy teploemkosti butilovykh spirtov vblizi KT (Russian Edition)

Izokhornaya teploemkost" (IT)- odno iz klyuchevykh termodinamicheskikh svoystv veshchestv dlya nauchnykh issledovaniy. Nadezhnye dannye ob IT veshchestva yavlyayutsya vazhnym instrumentom dlya issledovaniya fazovykh perekhodov i kriticheskikh yavleniy v zhidkostyakh i gazakh. Eto obuslovleno tem, chto IT ochen" chuvstvitel"nyy parametr dazhe dlya malykh strukturnykh izmeneniy v sisteme. N-butanol i ego izomery imeyut vazhnoe tekhnologicheskoe primenenie. Naprimer, superkriticheskiy butanol i ego izomery mogut byt" ispol"zovany kak kosol"venty v sverkhkriticheskiy rastvoritel" dlya povysheniya effektivnosti sverkhkriticheskoy flyuidnoy tekhnologii. V rabote provedeny: eksperimental"nye i teoreticheskie issledovaniya Yang-Yang anomalii kriticheskogo povedeniya i singulyarnogo diametra krivoy sosushchestvovaniya faz dlya proverki osnovnykh idey i polozheniy “zavershennogo” skeylinga kriticheskikh yavleniy; issledovanie prirody asimmetrii krivoy sosushchestvovaniya zhidkost"-gaz vblizi KT; Pokazano, chto singulyarnost" dvukhfaznoy IT obuslovlena za schet raskhodimosti vtorykh proizvodnykh davleniya nasyshchennykh parov i khimicheskogo potentsiala, no ikh vklady v raskhodimost" raznye v zavisimosti ot prirody veshchestva.Polucheny znacheniya parametra Yang-Yang anomalii.