Spin State Switching Triggered by Light: Both Spacer Length and Parity Influence the Thermal and Light-Induced Properties of Spin Crossover Coordination Polymers (German Edition)
Price 71.16 - 104.00 USD
book24.ru71.16 USD
EAN/UPC/ISBN Code
9783838102269
Author
Alina Absmeier
Producer
Книга по Требованию
Weight
236 gr
Year of production
2008
The influence of non-coordinating anions and spacer length of the ligand is analysed in extension of the systematic investigations into iron(II) spin cossover coordination polymers. Ditetrazole complexes of iron(II) perchlorate, tetrafluoroborate and hexafluorophosphate where the two tetrazole moieties are separated by alkylene spacers with different number of carbon atoms (n) are presented. Pronounced structural, optical, magnetic and magneto- optical changes are analysed and found in the comparison of the two series.The results allow a deeper insight in coherences between structural changes and electronic occupations, which can be detected as thermal, optical or magnetic spin transitions.